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Péligot's salt : ウィキペディア英語版
Potassium trioxochlorochromate

Potassium trioxochlorochromate,〔 potassium chlorochromate,〔(Synonyms Of Chemicals ). Csudh.edu (2003-09-16). Retrieved on 2011-06-01.〕 Peligot's salt, or Péligot's salt is a chemical substance named after Eugène-Melchior Péligot.〔Norm Stanley (Colorful Chromium Compounds ), 23 August 2002〕 Its formula is KCrO3Cl〔(Glossary ). Srb.npaci.edu. Retrieved on 2011-06-01.〕
Peligot's salt is the potassium salt of chlorochromic acid (chromic acid where chlorine has replaced one of the OH groups). Peligot's salt can be considered intermediate between chromic acid and chromyl chloride.〔
It is stable in air but in water, where it is soluble,〔 it can become hydrolysed. When under high temperature, Peligot's salt parts with its chlorine and produces chromic oxide.〔
Potassium chlorochromate can be prepared from potassium dichromate, hydrochloric acid, and water. The substance may look like long orange-red crystals.〔
Peligot's salt can oxidise the substance benzyl alcohol, a reaction which can be catalysed by acid.
The structure of Peligot's salt has been redeterminated in 2002.〔
==(18-Crown-6)potassium chlorochromate==

(18-Crown-6)potassium chlorochromate (1,4,7,10,13,16-hexaoxacyclooctadecane-k6O)potassium chlorochromate) or CrClO3 is a crystal structure that contains a K+ cation.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「Potassium trioxochlorochromate」の詳細全文を読む



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